Substituent-dependent spin-density distribution and coexistence of Fe 3d and π spins on ferrocene-tetrathiafulvalene hybrids.
نویسندگان
چکیده
Ferrocene (Fc) and tetrathiafulvalene (TTF) moieties were incorporated into novel hybrid molecules of structure FcS4TTF(R)2 (R = CF3 and SMe). [FcS4TTF(R)2](•+) exhibited R-dependent spin-density distribution, and [FcS4TTF(CF3)2](••2+) showed the coexistence of Fc-centered Fe 3d and TTF-centered π spins. The solid-state molecular structures in different oxidation states reflect their characteristic spin states.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 52 24 شماره
صفحات -
تاریخ انتشار 2013